By Jean Rouquerol, Visit Amazon's Françoise Rouquerol Page, search results, Learn about Author Central, Françoise Rouquerol, , Kenneth S.W. Sing

ISBN-10: 0125989202

ISBN-13: 9780125989206

The declared goal of this booklet is to supply an introductory evaluation of some of the theoretical and sensible points of adsorption by way of powders and porous solids with specific connection with fabrics of technological significance. the first target is to satisfy the desires of scholars and non-specialists, who're new to floor technological know-how or who desire to use the complicated suggestions now to be had for the choice of floor region, pore measurement and floor characterization. additionally, a serious account is given of contemporary paintings at the adsorptive homes of activated carbons, oxides, clays and zeolites. Key good points * presents a entire therapy of adsorption at either the gas/solid interface and the liquid/solid interface * comprises chapters facing experimental method and the translation of adsorption info received with porous oxides, carbons and zeolites * innovations catch the significance of heterogeneous catalysis, chemical engineering and the creation of pigments, cements, agrochemicals, and prescribed drugs

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Extra resources for Adsorption by powders and porous solids: principles, methodology, and applications

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5. An additional factor that contributes to the validity of the binary picture is the repulsion between the rare gas atoms. It limits the number of atoms that can simultaneously effectively couple to the vibration of the diatomic molecule. Under the binary approximation we can break the whole history of each cluster impact into a series of elementary steps. Each collision can be treated as an isolated one as is the case in the gas-phase, including the Chemistry under Extreme Conditions: Cluster Impact Activation 27 2500 60 fsec 2000 1500 1000 7 500 D w

The impact at the surface was described by a hard cube model. 1 0 0 We have compared the results of this approximation to results of simulations that used a full mechanical model of the solid 84 and to other approximations. 1 0 1 More details on the classical simulations can be found in the original papers. c Concerted four-center reactions are expected to have a high energetic barrier due to an unfavorable orbital correlation. 1 0 2 The high barrier for such reactions is due to a curve crossing between the state that originates in the ground state reactants and correlates to the electronically excited products and the state that originates in the electronically excited reactants and correlates to the ground state products.

Sections 4, 5 and 6 are arranged according to the consecutive stages of the impact of a cluster with a surface. First, in Sec. 4, we present the new and unique features of the reaction dynamics under the special condition within the impact-heated cluster. Special attention is given to the role of the cluster in determining the efficiency of the studied processes. Section 5 reports molecular dynamics (MD) simulations showing that the finite cluster very rapidly reaches thermal equilibrium and presents a simple mechanism for this facile equilibration.

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Adsorption by powders and porous solids: principles, methodology, and applications by Jean Rouquerol, Visit Amazon's Françoise Rouquerol Page, search results, Learn about Author Central, Françoise Rouquerol, , Kenneth S.W. Sing


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