By Stuart A. Rice, Aaron R. Dinner

ISBN-10: 0470143495

ISBN-13: 9780470143490

ISBN-10: 0470698284

ISBN-13: 9780470698280

The Advances in Chemical Physics sequence offers the chemical physics and actual chemistry fields with a discussion board for severe, authoritative reviews of advances in each region of the self-discipline. choked with state-of-the-art learn stated in a cohesive demeanour no longer discovered in other places within the literature, every one quantity of the Advances in Chemical Physics sequence serves because the excellent complement to any complex graduate type dedicated to the research of chemical physics.

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33 35 39 47 56 57 I. INTRODUCTION The thermodynamic description of nonequilibrium systems rests on the assumption that the usual thermodynamic functions can be defined for nonequilibrium states so that the relationship between them is that known from equilibrium systems. The range of validity of this thermodynamic hypothesis can be determined by considering a definite statistical-mechanical model of the irreversible process, and this has been done among others by Prigogine17.

V . Single Step, Unimolecular Reaction Detonation . . A . The Detonation Equations . . . . . . B . Ignition Temperature Model . . . . . C. Arrhenius Kinetics and Detonations in Real Gases References ....................... . . . . ... 60 96 104 110 115 121 128 * This work was carried out a t the University of Wisconsin Theoretical Chemistry Laboratory under Contract NOrd 15884 with the Naval Bureau Ordnance.

60 96 104 110 115 121 128 * This work was carried out a t the University of Wisconsin Theoretical Chemistry Laboratory under Contract NOrd 15884 with the Naval Bureau Ordnance.

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Advances in Chemical Physics, Volume 3 by Stuart A. Rice, Aaron R. Dinner


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