By Rainer Mahrwald

ISBN-10: 1402087004

ISBN-13: 9781402087004

ISBN-10: 1402087012

ISBN-13: 9781402087011

Aldol Reactions presents a finished up to date evaluation of aldol reactions including:

  • Application of other steel enolates
  • Catalytic aldol additions catalyzed via diversified Lewis acids and Lewis bases
  • Enantioselective direct aldol additions
  • Antibodies and enzyme catalyzed aldol additions
  • The contemporary competitive improvement of organocatalyzed aldol additions.

The energy of every technique is proven by way of a number of purposes in overall synthesis of normal items. the professionals and cons of those methodologies with reference to stereoselectivity, regioselectivity and alertness in overall synthesis of usual items are mentioned. nice significance is determined to the varied probabilities of the guide of aldol response to put in required configurations in complex traditional product synthesis.

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Sample text

59 Elaiolide belongs to the efomycines – a class of anti-inflammatory agents isolated from microorganisms. 14). 10 Boron enolate aldol additions in total synthesis of spongistatin An efficient synthesis of epothilone D analogs has been developed using highly stereoselective boron enolate aldol addition. 61 During the total synthesis of australine a defined configured stereopentad was required. r. r. 63 The α-oxygen-containing aldehyde 71 was deployed in a convergent total synthesis of pteridic acid A.

Wei HX, Jasoni RL, Dchao H, Hu J, Pare PW (2004) Tetrahedron 60:11829 17. (a) Fujisawa H, Sasaki Y, Mukaiyama T (2001) Chemistry Lett 3:190; (b) Li WDZ, Zhang XX (2002) Org Lett 4:3485 18. Willis MC, Cutting GA, John MP (2004) Synlett 1195 19. Yost JM, Zhou G, Coltart DM (2006) Org Lett 8:1503 20. Zhou G, Yost JM, Coltart DM (2008) Synthesis 478 21. Evans DA, Tedrow JS, Shaw JT, Downey CW (2002) J Am Chem Soc 124:392 22. Evans DA, Downey CW, Shaw JT, Tedrow JS (2002) Org Lett 4:1127 23. McNulty J, Nair JJ, Sliwinski M, Harrington LE, Pandey S (2007) Eur J Org Chem 5669 24.

Mahrwald R (1995) Tetrahedron 51:9015 13. Sano S, Miwa T, Liu XK, Shii T, Takehisa T, Shiro M, Nagao Y (1998) Tetrahedron: Asymm 9:3615 14. Wei HX, Li K, Zhang Q, Jasoni RL, Hu J, Pare PW (2004) Helv Chim Acta 87:2354 15. Wei HX, Hu J, Jasoni RL, Li G, Pare PW (2004) Helv Chim Acta 87:2359 16. Wei HX, Jasoni RL, Dchao H, Hu J, Pare PW (2004) Tetrahedron 60:11829 17. (a) Fujisawa H, Sasaki Y, Mukaiyama T (2001) Chemistry Lett 3:190; (b) Li WDZ, Zhang XX (2002) Org Lett 4:3485 18. Willis MC, Cutting GA, John MP (2004) Synlett 1195 19.

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Aldol Reactions by Rainer Mahrwald

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